ArticleACS omega2026
Uranyl Recognition through Cucurbit[7]uril-Bipyridinium Carboxylate Pseudorotaxanes as Supramolecular Chelators.
Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Exploration of new ligands for actinide recognition is desirable for developing more efficient separation processes, and pseudorotaxane-type supramolecular complexes have the attributes of simple synthesis and structural adaptability. In this work, we propose two novel CB[7]-based bipyridinium carboxylate pseudorotaxane ligands and evaluate their potential as efficient chelators for uranyl recognition. A combination of characterization methods including nuclear magnetic resonance (NMR), fluorescence analysis, mass spectrometry (ESI-MS), infrared spectroscopy (IR), and single-crystal X-ray diffraction (SCXRD), together with theoretical calculation, demonstrates the feasibility of such a kind of pseudorotaxane chelator for uranyl recognition via host-guest synergistic chelation. This work establishes a new type of cucurbituril-carboxylate supramolecular chelator and will inspire the development of more other supramolecular ligands for actinide recognition.
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