ArticleNature communications2026
Anodic coordination polymerization for bilayer passivation of copper against oxidation.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed.
- A Review of Recent Advances in Conversion and Self-Assembled Anti-Corrosion Films for Copper and Its Alloys.Molecules (Basel, Switzerland) · 2026Review
- Functional Hydrogel-Based Flexible Thermoelectric Generators: Principles, Mechanism, and Emerging Applications.Gels (Basel, Switzerland) · 2026Review
- Anodic coordination polymerization for bilayer passivation of copper against oxidation.Nature communications · 2026Article
Corrections and comments
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Authors and funding
13 authors.
Funding
Abstract
Copper corrosion under elevated temperature, humidity, and salinity environments has always been an important challenge in the engineering application. To enhance the corrosion protection of copper, an anodic oxidation induced coordination polymerization strategy was proposed, in which copper ions are released and in situ coordinated with 1,4-benzenedithiol (BDT) molecules to construct a bilayer passivation film, which consists of an outer Cu-BDT coordination polymer layer (~5.2 nm) and an intermediate cuprous sulfide layer (~ 1.8 nm) intrinsically grown on the underlying copper substrate. This passivation film markedly improves corrosion resistance, reducing the corrosion current density over three orders of magnitude in salinity environments. It also demonstrates chemical and thermal stability under acidic, alkaline, and high-temperature conditions. DFT calculations demonstrate that the passivation film increases the adsorption energy barriers of corrosive species, including O
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Registered trials
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