ArticleChemical science2026
Conversion of trifluoromethyls into esters along with polyether upcycling
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Ester and trifluoromethyl groups play crucial roles in chemistry and drug design. However, the implementation of interconversion from a trifluoromethyl into an ester under wide conditions is not an easy task, because the C-F bond of the trifluoromethyl group possesses high bond energy and is extremely difficult to break. Herein, we present for the first time a silylium-ion-initiated method for intermolecular C-F/C-O metathesis, enabling selective activation of inert C(sp
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