ArticleACS applied polymer materials2026
[2.2]Paracyclophane-Based Polyimides of Intrinsic Microporosity for Gas Separation.
Article in ACS applied polymer materials, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Polyimides (PIs) are a significant class of high-performance polymers due to their exceptional thermal, mechanical, and chemical stability. Their combination with polymers of intrinsic microporosity (PIMs) provides access to materials with structural robustness coupled with permanent microporosity. Progress in this area is frequently constrained by the limited availability of difficult-to-prepare and structurally complex dianhydrides. Building on our recent work on [2.2]-paracyclophane (PCP)-based PIMs for gas sorption, we report a series of PCP-polyimide PIMs synthesized from PCP-derived dianhydrides and amino-PCP monomers. The preparation of these dianhydrides enabled a systematic investigation of the monomer structure and connectivity. Two polymer families were obtained: PCP-PIs incorporating pseudo-
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