ArticleScience advances2026
Ion trap membrane with confined bind-jump strategy for high-efficiency direct lithium extraction.
Article in Science advances, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Enhancing Lithium Binding Affinity, Exchange Rate, and Hard-Soft Selectivity of Catenane Ligands by Post-Interlocking Modification.Inorganic chemistry · 2026Article
- Bio-Inspired and Synergistic Ion Transport: Advancing the Frontiers of Lithium Extraction From Complex Aqueous Sources.ChemPlusChem · 2026Review
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Authors and funding
6 authors.
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Abstract
The rapidly growing demand for lithium in energy storage technologies necessitates more efficient lithium extraction methods from salt lakes. Direct lithium extraction (DLE) has gained attention, as it addresses more than 50% lithium losses in traditional salt-pond-based processes. However, separating lithium ion from sodium ion or potassium ion remains challenging due to their similar charge and hydration radii. To overcome this, we developed a covalent organic framework-based ion trap membrane by embedding lithiophilic diketone molecules [2-thenoyltrifluoroacetone (HTTA)] into subnanometer channels, enabling a "bind-jump" transport mechanism. HTTA sites selectively bind lithium ion, assist its partial dehydration (bind step), and promote hopping to adjacent HTTA sites (jump step). The optimized HTTA
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