ArticleEnvironmental geochemistry and health2026
Copper extraction and phytotoxicity of organic acid leached mine tailings in Brassica napus.
Article in Environmental geochemistry and health, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Mine tailings pose environmental hazards but can also contain economically valuable metals like copper (Cu). Organic solvents, particularly low molecular weight organic acids (LMWOAs), are natural and biodegradable acids with great potential for Cu removal and tailings remediation. We evaluated the potential of citric, malic, maleic, malonic and lactic acids (concentration of 1 M) in extracting Cu from legacy Cu-tailings, as well as their phytotoxicity risk. Brassica napus was grown in tailings leached by LMWOAs at three dilutions (1/4, 1/16, 1/128) to simulate solvent biodegradation or dilution by rainfall. Plant height, biomass, chlorophyll, shoot green cover and leachate metal concentrations (Al, Ca, Cu, Fe, K, Mg, Mn, V, Zn) were measured; deionised water was used as a control. At 1/4 dilution, citric, malic, and malonic acids generated the highest Cu concentrations in leachate (625-965 mg L
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