Evidence map›Paper›PMID 41979650›Full record

ArticleAnalytical and bioanalytical chemistry2026

Determination of three previously unidentified polycyclic aromatic hydrocarbons of molecular mass 302 Da in particulate Standard Reference Materials (SRMs) and combustion-related samples.

Ioannis Sadiktsis, Vilhelm B Malmborg, Andres D Campiglia, Fernando J Uribe-Romo, Stephen A Wise

Abstract read
PubMed Publisher
In one paragraph

Article in Analytical and bioanalytical chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Ioannis SadiktsisDepartment of Chemistry, Stockholm University, 10691, Stockholm, Sweden. ioannis.sadiktsis@su.se.ORCID http://orcid.org/0000-0002-1598-7093
Vilhelm B MalmborgErgonomics and Aerosol Technology, LTH, Lund University, 22100, Lund, Sweden.ORCID http://orcid.org/0000-0002-4362-1646
Andres D CampigliaDepartment of Chemistry, University of Central Florida, Physical Sciences Building, 4111, Orlando, FL, 32816, USA.ORCID http://orcid.org/0000-0003-1918-2708
Fernando J Uribe-RomoDepartment of Chemistry, University of Central Florida, Physical Sciences Building, 4111, Orlando, FL, 32816, USA.ORCID http://orcid.org/0000-0003-0212-0295
Stephen A WiseNational Institute of Standards and Technology (NIST), Gaithersburg, MD, 20899, USA.ORCID http://orcid.org/0000-0002-0021-1970

Funding

Svenska Forskningsrådet Formas 2021-00496
6 · The paper itself

Abstract

Polycyclic aromatic hydrocarbons (PAHs) of molecular mass (MM) 302 Da comprise numerous structural isomers that are of high concern for human health. Because of their multiplicity, low abundance in the environment, and limited availability of authentic standards, their occurrence, composition, and environmental health risk remain not well characterized. Here we extend the characterization of MM 302 Da PAH isomers in combustion-related particulate matter with the addition of four newly synthesized and previously unidentified MM 302 Da isomers: dibenzo[a,l]fluoranthene (DBalF), dibenzo[b,l]fluoranthene (DBblF), dibenzo[a,j]fluoranthene (DBajF), and naphtho[2,1-j]fluoranthene (N21jF). Using a coupled high-performance liquid chromatography/gas chromatography-mass spectrometric system with a 50% phenyl methylpolysiloxane stationary phase, 24 MM 302 Da isomers were annotated in four Standard Reference Materials, SRM 1648a, SRM 1649b, SRM 1650b, and SRM 2975, and in four combustion-related particulate matter samples consisting of two traffic-impacted filters and two laboratory-generated combustion samples. Three of the four previously unidentified compounds, DBalF, DBajF, and N21jF, were chromatographically resolved and quantified for the first time in these samples. Quantitative analysis of nine MM 302 Da PAHs (∑MM302Da) showed that these compounds accounted for roughly 0.66-4.1% of the total mass for 50 PAHs. The previously unidentified isomers were recurring but generally minor contributors to the ∑MM302Da burden, with N21jF representing 8-14%, DBalF typically 6-10% (but 23% in SRM 2975), and DBajF varying between 1 and 5%. These results demonstrate both the ubiquity and compositional variability of MM 302 Da PAHs in combustion-derived particulate matter and provide new reference data for analytical investigations of MM 302 Da PAHs.

Indexed as

Combustion-related particulate matterGas chromatography (GC)Mass spectrometry (MS)MM 302 Da PAHPolycyclic aromatic hydrocarbons (PAHs)Standard Reference Materials (SRMs)

Identifiers

PMID41979650

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.