Evidence map›Paper›PMID 41978563›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Converting 1,1-Bisborylalkanes into 1,2-Bisborylalkanes Enabled by Iron Ligand-to-Metal Charge Transfer (LMCT) Photocatalysis.

Zheye Zhang, George Chen, Michael Li, Carla Slebodnick, Diego Troya, Ming Chen

Abstract read
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In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Zheye ZhangDepartment of Chemistry, Virginia Tech, Blacksburg, Virginia, USA.
George ChenDepartment of Chemistry, Virginia Tech, Blacksburg, Virginia, USA.
Michael LiDepartment of Chemistry, Virginia Tech, Blacksburg, Virginia, USA.
Carla SlebodnickDepartment of Chemistry, Virginia Tech, Blacksburg, Virginia, USA.
Diego TroyaDepartment of Chemistry, Virginia Tech, Blacksburg, Virginia, USA.
Ming ChenDepartment of Chemistry, Virginia Tech, Blacksburg, Virginia, USA.ORCID https://orcid.org/0000-0002-9841-8274

Funding

Asymmetric Synthesis via Organoboron CompoundsR35GM147523 · NIGMS · VIRGINIA POLYTECHNIC INST AND ST UNIV · PI Ming Chen · 2022 to 2026
$1.9M
National Science Foundation 1726077NIGMS NIH HHS R35 GM147523NIH HHS R35 GM147523-01Virginia Tech Chemistry NMR Facility
6 · The paper itself

Abstract

We report herein a strategy to convert 1,1-bisborylalkanes into 1,2-bisborylalkanes through iron ligand-to-metal charge transfer (LMCT) photocatalysis. Under the optimized conditions, 1,1-bisborylalkanes undergo hydrogen atom abstraction to generate an initial radical intermediate. Subsequent radical-induced 1,2-boryl group migration furnishes an open-shell species that is more stable thermodynamically. The resulting carbon-centered radical can be intercepted by electron-deficient alkenes, affording a range of synthetically useful 1,2-bisborylalkanes.

Indexed as

1,1‐bisborylalkanes1,2‐bisborylalkanesiron catalysisligand‐to‐metal charge transfer (LMCT)photocatalysis

Identifiers

PMID41978563
PMCPMC13206249

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.