ArticlePhysical chemistry chemical physics : PCCP2026
Photoswitching behaviour of quinoline-substituted bicyclooctadienes and the role of protonation.
Article in Physical chemistry chemical physics : PCCP, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Molecular Solar-Thermal (MOST) systems employ photoswitches that convert solar energy into chemical energy in the form of a metastable isomer and release it as heat upon triggering. An example of such a photoswitch is bicyclooctadiene (BOD), which is converted into its higher energy photoisomer, tetracyclooctane (TCO), by a [2+2] cycloaddition upon UV light irradiation. Despite their potential as MOST candidates due to a high calculated energy storage density of ≈ 1.77 MJ kg
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