Calorimetry informed visual digital model for continuous flow photobromination.

Yiming Xu, Yun Zou, Junfei Zhang, Fujun Li, Shengyang Tao

Abstract read

In one paragraph

Article in Communications chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Yiming Xu *State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemistry, Dalian University of Technology, Dalian, China.

Yun Zou *State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemistry, Dalian University of Technology, Dalian, China.

Junfei Zhang *State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemistry, Dalian University of Technology, Dalian, China.

Fujun LiState Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemistry, Dalian University of Technology, Dalian, China.

Shengyang TaoState Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemistry, Dalian University of Technology, Dalian, China. taosy@dlut.edu.cn.ORCID http://orcid.org/0000-0002-0567-8860

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22372025

6 · The paper itself

Abstract

Calorimetry data for continuous-flow photochemistry are scarce, hindering kinetic model development and safe scale-up. Here we show that in situ calorimetry combined with designed experiments enables a quantitative, heat-consistent kinetic description for the continuous-flow photobromination of (E)-methyl 2-(methoxyimino)-2-(o-tolyl) acetate (EMMA). We record total heat release, conversion, and selectivity over defined windows of residence time and light intensity, and fit a two-step kinetic scheme constrained by the calorimetric heat-release data. The model predicts total heat with R

Identifiers

PMID41965807

DOI10.1038/s42004-026-02023-5

PMCPMC13266058

What OpenQuestion holds

Textmetadata

LicenceCC BY

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.