ArticleChemical science2026
Change of the aromatic nature through face-to-face stacking.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Molecular Aromaticity from a Magnetic Perspective.The journal of physical chemistry letters · 2026Article
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Authors and funding
3 authors.
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No grant is acknowledged in the PubMed record.
Abstract
We have computationally studied the aromatic nature of molecules built from tetraoxa-isophlorin (TOI) and Ni(ii)-norcorrole (NiNc) moieties. Calculations of the magnetically induced current density (MICD) susceptibility and magnetically induced ring currents (MIRC) show that antiaromatic porphyrinoids form bound aromatic stacked dimers with a distance of about 3 Å between the monomers. We design molecules consisting of many antiaromatic rings because they bind stronger due to the aromatic stabilization and a formal double bond between the individual pairs of the molecular rings of the stacked dimers. Global conjugation and strong coupling between the antiaromatic moieties can be prevented by introducing linkers with formal single bonds between the antiaromatic rings. Cyclooctatetraene (COT) with two ethynyl groups in the
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