Evidence map›Paper›PMID 41952347›Full record

ArticleJournal of the American Chemical Society2026

Femtosecond-to-Second Time-Resolved Spectroscopy Brings Unparalleled Insight Into the Life Cycle of the Versatile Manganese Photocatalyst [Mn

Jonathan B Eastwood, Conor D Rankine, Thomas J Burden, Abigail Frith, L Anders Hammarback, Barbara Procacci, Daniel J Shaw, Benjamin R O'Donoghue, Ian P Clark, Gabriel Karas and 7 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

17 authors.

Jonathan B EastwoodDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0000-0001-5586-7697
Conor D RankineDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0000-0002-7104-847X
Thomas J BurdenDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0000-0001-9418-686X
Abigail FrithDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0009-0009-8770-787X
L Anders HammarbackDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0000-0003-1336-6848
Barbara ProcacciDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0000-0001-7044-0560
Daniel J ShawDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0000-0003-0090-2947
Benjamin R O'DonoghueDepartment of Chemistry, University of York, York YO10 5DD, U.K.
Ian P ClarkCentral Laser Facility, Research Complex at Harwell, STFC, Rutherford Appleton Laboratory, Harwell Campus, Oxfordshire, Didcot OX11 0QX, U.K.ORCID 0000-0002-0105-4743
Gabriel KarasCentral Laser Facility, Research Complex at Harwell, STFC, Rutherford Appleton Laboratory, Harwell Campus, Oxfordshire, Didcot OX11 0QX, U.K.
Partha MalakarCentral Laser Facility, Research Complex at Harwell, STFC, Rutherford Appleton Laboratory, Harwell Campus, Oxfordshire, Didcot OX11 0QX, U.K.ORCID 0000-0001-6874-7010
Gregory M GreethamCentral Laser Facility, Research Complex at Harwell, STFC, Rutherford Appleton Laboratory, Harwell Campus, Oxfordshire, Didcot OX11 0QX, U.K.ORCID 0000-0002-1852-3403
Michael TowrieCentral Laser Facility, Research Complex at Harwell, STFC, Rutherford Appleton Laboratory, Harwell Campus, Oxfordshire, Didcot OX11 0QX, U.K.ORCID 0000-0002-1305-701X
Neil T HuntDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0000-0001-7400-5152
Gerard P McGlackenSchool of Chemistry, Analytical & Biological Chemistry Research Facility, University College Cork, Cork T12 YN60, Ireland.ORCID 0000-0002-7821-0804
Ian J S FairlambDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0000-0002-7555-2761
Jason M LynamDepartment of Chemistry, University of York, York YO10 5DD, U.K.ORCID 0000-0003-0103-9479

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Visible-light-activated radical photoinitiators are pivotal in the efficient construction of complex molecular architectures and the precision synthesis of advanced polymeric materials. At the heart of their function lies the formation of reactive radical species that drive selective homolytic bond cleavage, but elucidating the fundamental mechanisms of these processes is notoriously difficult due to the fleeting nature of key intermediates. In this study, time-resolved infrared (TRIR) spectroscopy provides a powerful window into the complete reaction profile of the versatile photocatalyst [Mn

Identifiers

PMID41952347
PMCPMC13107439

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.