ArticleChemical communications (Cambridge, England)2026
Time-resolved IR and X-ray spectroscopy as complementary electronic structure probes of photoinduced ligand-exchange in molybdenum hexacarbonyl.
Article in Chemical communications (Cambridge, England), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Photoinduced ligand-exchange dynamics in molybdenum hexacarbonyl have been studied using time-resolved IR and X-ray spectroscopy. We find that the energies of the unoccupied molybdenum 4d-derived orbitals that are accessed through X-ray transitions correlate with red-shifts in CO stretching modes. This provides complementary electronic structure information from the metal and the ligand perspective.
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