ArticleAngewandte Chemie (International ed. in English)2026
Dithioketal Polymers Via Radical Polymerization of γ-Dithiobutyrolactone.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Functional cyclic disulfides enable multi-pathway degradable polyvinyls.Chemical science · 2026Article
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6 authors.
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Abstract
Polymers bearing in-chain dithioketal groups are an emerging class of materials with specific properties like reactive oxygen species (ROS)-responsiveness and vitrimer-type behavior. Until now, these polymers have been exclusively produced by step-growth polymerization or polyaddition; herein, we report the first chain polymerization leading to dithioketal polymers. γ-dithiobutyrolactone (DTBL) is radically copolymerized with a series of conjugated monomers to yield copolymers with ring-retained dithioketal units exclusively. DFT calculations rationalize the contrasting behaviors of DTBL and its thionolactone analogue γ-thionobutyrolactone (TBL), highlighting how electronic effects of the ring heteroatoms govern propagation efficiency and ring-retention versus ring-opening pathways. The ability of DTBL to bring degradability to thermosets, latexes, and RAFT-derived complex architectures is revealed.
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