ArticleJournal of the American Chemical Society2026
Hierarchical Oil-Water-Oil Pickering Double Emulsions Stabilized by Tubular Nanoparticles.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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8 authors.
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Abstract
Pickering emulsions stabilized by a small fraction of submicrometer-size clay tubes provide stable and tunable soft-matter systems with relevance across multiple fields. We here introduce a novel oil-in-water-in-oil Pickering double emulsion system stabilized by selectively functionalized halloysite nanotubes. The stability of the double emulsions was achieved through the combined use of pristine and surface-modified halloysite nanotubes, which selectively stabilized the oil-in-water and water-in-oil interfaces in the two separately prepared colloids. After these two samples were mixed and stirred, a hierarchical structure of oil microdroplets inside water droplets dispersed in bulk oil was obtained. Fluorescent microscopy and particle-tracking analyses confirmed that oil droplets confined within the double emulsion exhibit Brownian motion with decreased diffusion coefficients. The resulting dual-compartment structure enables the simultaneous encapsulation of hydrophilic and hydrophobic species, promising applications in controlled delivery and multifunctional formulations.
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