ArticleACS omega2026
New Insights into Radical Mechanisms in Natural Drying Oils: Paint Binders as Reactors for Nanoparticle Formation.
Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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8 authors.
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Abstract
Understanding radical processes in drying oils is essential for both heritage science and materials chemistry, as these reactions govern film formation and long-term stability in historical paintings. In this study, we investigate radical mechanisms in linseed oil, a traditional paint binder. Gold salts are used as probes to elucidate film-drying reactions. The introduction of gold salts into both raw and lead-treated linseed oils leads to the formation of gold nanoparticles, whose size, morphology, and distribution are monitored by spectroscopic methods and transmission electron microscopy (TEM). Under ambient conditions, spherical gold nanoparticles form during the drying of both oil types. Electron paramagnetic resonance (EPR) reveals oxygen-centered radicals (peroxyl (ROO
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