ArticleInorganic chemistry2026
Synthesis and Structure of Group 13 POCOP Complexes.
Article in Inorganic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In this study, we explore the coordination complexes of the resorcinol bis(diphenylphosphinite) (POCOP) pincer ligand with Group 13 (aluminum, gallium and indium) metal centers. We report the synthesis of six new Group 13 POCOP complexes that have all been structurally characterized. The aluminum and indium complexes all crystallize in a five-coordinate "closed" geometry; however, for gallium, an "open" four-coordinate complex is additionally observed in the solid state, similar to an intramolecular frustrated Lewis pair.
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