ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
[Ti(py)
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Access to defined titanium(II) compounds is crucial for their use in synthesis and catalysis. Most established routes to Ti(II) compounds rely on the reduction of Ti(III) or Ti(IV), an approach that intrinsically limits atom efficiency and can introduce byproducts or lead to mixed-valency complexes. Here, an alternative strategy for obtaining Ti(II) is presented, based on the oxidation of Ti metal by iodine. Ti diiodide formed in this reaction is subsequently complexed to afford the novel Ti(II) complex [Ti(py)
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