ArticleInorganic chemistry2026
Golden Molecular Tweezers: Dinuclear Corannulene-Au(I) Acetylide Hosts for Fullerene Binding.
Article in Inorganic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A series of homonuclear bimetallic organometallic complexes bearing two Au(I) atoms and two corannulene fragments have been synthesized, and their fullerene recognition properties were extensively studied in solution. The tether groups were diphosphine ligands with variable rigidity (namely, dppe, dppf, dppbenz, and xantphos) to cover a range of potential semisupported intramolecular aurophilic interactions. Experimental results showed that neither extreme flexibility nor rigidity favors fullerene binding, and in those cases where the metallophilic contact is present and assured by ligand design, this force might hinder the supramolecular assembly formation. Computational calculations clearly indicate that the aurophilic interaction is just another force that is playing a moderate role within the manifold forces involved in the recognition process. The most notable finding corresponded to host
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