Evidence map›Paper›PMID 41911410›Full record

ArticleMacromolecular rapid communications2026

Spectroscopic Ellipsometry of Conducting Anisotropic Pedot thin Films.

Francesco Bisio, Katia Sparnacci, Angelo Angelini, Martina Martusciello, Daniela Di Fonzo, Davide Comoretto, Maddalena Patrini

Abstract read
In one paragraph

Article in Macromolecular rapid communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Micro- and Nanopatterning of Highly Conductive PEDOT Thin Films.Macromolecular rapid communications · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Francesco BisioDipartimento Di Scienze e Innovazione Tecnologica, Università degli Studi del Piemonte Orientale, Alessandria, Italy.ORCID https://orcid.org/0009-0003-3658-1804
Katia SparnacciDipartimento Di Scienze e Innovazione Tecnologica, Università degli Studi del Piemonte Orientale, Alessandria, Italy.ORCID https://orcid.org/0000-0003-2102-9649
Angelo AngeliniAdvanced Materials Metrology and Life Science Division, INRiM Institute (Istituto Nazionale Di Ricerca Metrologica), Torino, Italy.ORCID https://orcid.org/0000-0001-5332-6686
Martina MartuscielloDipartimento di Chimica e Chimica Industriale, Università degli Studi di Genova, Genova, Italy.
Daniela Di FonzoDipartimento di Chimica e Chimica Industriale, Università degli Studi di Genova, Genova, Italy.
Davide ComorettoDipartimento di Chimica e Chimica Industriale, Università degli Studi di Genova, Genova, Italy.ORCID https://orcid.org/0000-0002-2168-2851
Maddalena PatriniDipartimento di Fisica Alessandro Volta, Università degli Studi di Pavia, Pavia, Italy.ORCID https://orcid.org/0000-0003-3559-1384

Funding

Italian Ministry of University and Research 2020TS9LXSMinistero dell'Università e della Ricerca 2020TS9LXS
6 · The paper itself

Abstract

We report a comprehensive spectroscopic investigation of poly[3,4-ethylenedioxythiophene] (PEDOT) thin films, including both those synthesized from solution in the doped state and from commercial PEDOT:PSS (poly(styrene sulfonate)) formulations. Variable-angle spectroscopic ellipsometry is combined with transmittance and reflectance measurements spanning the UV to mid-infrared spectral range. Data from the different techniques are consistently analyzed within a unified framework based on the complex dielectric function of each film. Uniaxial optical modeling assuming an edge-on molecular orientation reveals a markedly anisotropic response, with the ordinary (in-plane) component exhibiting significantly higher conductivity than the out-of-plane dielectric component. Notably, the synthesized PEDOT films show enhanced in-plane optical conductivity, in agreement with sheet resistance measurements. The molecular structure and anisotropy of PEDOT are further corroborated by grazing-incidence wide-angle X-ray scattering (GIWAXS), which reveals an intra-lamellar structure characterized by π-π stacking of PEDOT chains at a distance of approximately 3.9 Å and an interlamellar periodicity of about 15.7 Å. Overall, these results represent a significant step toward a deeper understanding of the electronic and optical properties of this distinctive class of macromolecules and their potential use in photonics and optical metamaterials.

Indexed as

Bridged Bicyclo Compounds, HeterocyclicPolymersAnisotropyElectric ConductivityMolecular StructurePolystyrenesBridged Bicyclo Compounds, Heterocyclicpoly(3,4-ethylene dioxythiophene)PolymersPolystyrenesanisotropyconducting polymersellipsometryoptical functionsPEDOTthin films

Identifiers

PMID41911410
PMCPMC13238304

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.