Evidence map›Paper›PMID 41908452›Full record

ArticleACS omega2026

Molecular Constraints and Electronic Structure Direct Multi-Step PCET Mechanisms in the Electrochemical Oxidation of Ruthenium Complexes.

Laura C Castaño Castañeda, Bruno Angelillo, Brandon Q Mercado, Florencia Di Salvo, Mauricio Cattaneo

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Laura C Castaño CastañedaINQUINOA (CONICET-UNT), Facultad de Bioquímica, Química y Farmacia, Instituto de Química Física, Universidad Nacional de Tucumán, Ayacucho 471, San Miguel de Tucumán 4000, Argentina.
Bruno AngelilloINQUINOA (CONICET-UNT), Facultad de Bioquímica, Química y Farmacia, Instituto de Química Física, Universidad Nacional de Tucumán, Ayacucho 471, San Miguel de Tucumán 4000, Argentina.
Brandon Q MercadoDepartment of Chemistry, Yale University, 225 Prospect Street, New Haven, Connecticut 06520, United States.ORCID https://orcid.org/0000-0002-1940-3497
Florencia Di SalvoINQUIMAE (CONICET-UBA), Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2160. Ciudad Universitaria, Plaza Gregorio Klimovsky, Pabellón II, Ciudad Autónoma de Buenos Aires (CABA) C1428EGA, Argentina.ORCID https://orcid.org/0000-0001-7295-2471
Mauricio CattaneoINQUINOA (CONICET-UNT), Facultad de Bioquímica, Química y Farmacia, Instituto de Química Física, Universidad Nacional de Tucumán, Ayacucho 471, San Miguel de Tucumán 4000, Argentina.ORCID https://orcid.org/0000-0002-5598-0814

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Extensive studies on the dehydrogenative oxidation of alkylamines on transition metals represent a generalized reactivity, with some reports on accessible intermediates and reactive species offering different interpretations. Here, the electrochemical oxidation of ruthenium amine complexes is examined to evaluate the reactivity of high-valent species. We report a combined spectroelectrochemical and DFT study of the complexes [Ru

Identifiers

PMID41908452
PMCPMC13019383

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.