Electronic-State Polarization Engineering-Regulated Fluorinated Covalent Organic Framework Nanocables for Fast Lithium-Ion Storage.

Kaifu Xu, Jianfei Shi, Yuting Qin, Di He, Chengyin Wang, Tianyi Wang

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Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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Authors and funding

6 authors.

Kaifu XuSchool of Chemistry & Materials, Yangzhou University, Yangzhou, Jiangsu, China.

Jianfei ShiSchool of Chemistry & Materials, Yangzhou University, Yangzhou, Jiangsu, China.

Yuting QinSchool of Chemistry & Materials, Yangzhou University, Yangzhou, Jiangsu, China.

Di HeSchool of Chemistry & Materials, Yangzhou University, Yangzhou, Jiangsu, China.

Chengyin WangSchool of Chemistry & Materials, Yangzhou University, Yangzhou, Jiangsu, China.

Tianyi WangSchool of Chemistry & Materials, Yangzhou University, Yangzhou, Jiangsu, China.ORCID https://orcid.org/0000-0002-0961-5285

Funding

National Natural Science Foundation of China 22472145Postgraduate Research & Practice Innovation Program of Jiangsu Province KYCX24_3729

6 · The paper itself

Abstract

Covalent organic frameworks (COFs) are promising anode materials for lithium-ion batteries (LIBs) owing to their tunable porous structures and abundant redox-active sites; however, insufficient electronic-structure regulation and sluggish kinetics severely limit their rate capability and cycling stability. Herein, an electronic-state polarization engineering strategy is proposed by in situ constructing fluorinated COF nanocables enriched with multipolar C─F units on conductive carbon nanotube scaffolds to form a high-performance anode (F-COF@CNT). The strong polarity of C─F bonds induces localized electronic polarization within the COF framework, enhancing electrostatic attraction toward Li

Indexed as

electronic‐state polarization engineeringfluorinated covalent organic frameworkhigh‐rate lithium‐ion storageorganic anode materials

Identifiers

PMID41904940

DOI10.1002/advs.75084

PMCPMC13285149

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