ArticleJournal of the American Chemical Society2026
Synthesis of 1,3-Dienes from Alkenes via Alkenyl Thianthrenium Salts.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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4 authors.
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Abstract
Herein, we show the conversion of alkenes into functionalized 1,3-dienes in two steps. First, C-H thianthrenation is used to access a wide pool of alkenyl electrophiles directly from alkenes. Second, the alkenyl thianthrenium salts undergo a Pd-catalyzed three-component coupling reaction with allene gas and nonorganometallic nucleophiles to afford 1,3-dienes. This method provides a robust and modular platform for accessing structurally complex 1,3-dienes that would be challenging to access otherwise.
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