ArticleInorganic chemistry2026
Boragerma[5]pyramidanes via a Germole-to-Borole Rearrangement.
Article in Inorganic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
The scope and limitations of a germole-to-borole rearrangement are reported. Double salt metathesis reactions of dipotassium germolediides with amino-, aryl-, and ferrocenyl-substituted boron dihalides allow for the preparation of borole complexes of Ge(II) in synthetically useful yields and quantities. The analogous silole-to-borole transformation is viable but is less selective and of limited synthetic use. The analysis of the molecular and electronic structure of the obtained Ge(II) borole complexes classifies them as boragerma[5]pyramidanes, molecular
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