ArticleNature communications2026
Microporous MOF for simultaneous high thermodynamic and kinetic synergistic separation of propylene and propane.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Efficient separation of propylene from propane is a critical yet challenging industrial process. While rigid molecular sieves offer ideal selectivity, their narrow nanopores inherently constrain adsorption capacity and diffusion kinetics due to compromised thermodynamic-kinetic trade-offs. To address this, we report ZSTU-10, a molecular sieve constructed via structure-directing agents. Uniquely, ZSTU-10 features localized sieving gates for selective guest admission, expansive diffusion channels for rapid transport, and central pore cavities for high-capacity storage. This gate-channel-cavity architecture enables the precise exclusion of propane while facilitating the dense packing and fast diffusion of propylene, achieving simultaneous thermodynamic-kinetics optimization in molecular sieving. Static adsorption experiments demonstrate an exceptional propylene uptake (97.7 cm
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