ArticleACS catalysis2026
Coordination-Induced Spin Modulation: Overcoming Spin Blocking in C-H Methylation with High-Spin Ferrous Complexes.
Article in ACS catalysis, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Asymmetric Iron-Catalyzed Vicinal C(spAngewandte Chemie (International ed. in English) · 2026Article
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Authors and funding
3 authors.
Funding
Abstract
Understanding spin state changes and their influence on the reactivity of earth-abundant transition metal complexes is essential for unlocking the full potential of these elements. While precedented in biological contexts and related model complexes, control of metal spin state is underexplored as a mode for reactivity control in organometallic chemistry. Here we describe coordination-induced spin modulation as a strategy to overcome spin blocking to enable C-H functionalization with four-coordinate high-spin iron(II) dimethyl complexes. Addition of monodentate phosphines induced room-temperature C-H methylation of arenes, while evaluation of sterics and σ-donacity demonstrated PhPMe
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