ArticleMikrochimica acta2026
Electrochemical sentinels: freestanding MnOx-laser-induced graphene electrodes for sensitive fenitrothion monitoring in food.
Article in Mikrochimica acta, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A freestanding manganese oxide nanoparticle–decorated laser-induced graphene electrode (MnOx-LIGE) for sensitive electrochemical detection of the organophosphate insecticide fenitrothion (FT) is reported. The electrode is fabricated via a one-step laser-engraving process on MnCl₂-doped polyimide films, enabling the simultaneous formation of porous graphene and in situ decoration with MnOx nanoparticles. Structural characterization confirms a three-dimensional porous graphene network uniformly decorated with MnOx nanoparticles, providing abundant active sites and accelerated electron transfer. Benefiting from this architecture, the MnOx-LIGE exhibits a wide linear detection range from 100.0 nmol/L to 250.0 µmol/L with a low detection limit of 13.66 nmol/L. Integrated with a portable electrochemical workstation, the sensor demonstrates excellent selectivity and stability. It achieves reliable recoveries of 102.4–104.2% in mango samples, highlighting its potential for rapid on-site monitoring of pesticide residues.
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