Evidence map›Paper›PMID 41862472›Full record

ArticleNature communications2026

Ultrathin crown ether-based polyamide membrane for ion-ion separations.

Luis Francisco Villalobos, Junwei Zhang, Junwoo Lee, Alex T Hall, Ryan M DuChanois, Camille Violet, John Cumings, Mingjiang Zhong, Menachem Elimelech

Abstract read
In one paragraph

Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Luis Francisco VillalobosMork Family Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, CA, USA. lf.villalobos@usc.edu.ORCID http://orcid.org/0000-0002-0745-4246
Junwei ZhangDepartment of Chemical and Environmental Engineering, Yale University, New Haven, CT, USA.ORCID http://orcid.org/0009-0002-8338-0872
Junwoo LeeDepartment of Chemical and Environmental Engineering, Yale University, New Haven, CT, USA.
Alex T HallDepartment of Materials Science and Engineering, University of Maryland, College Park, MD, USA.
Ryan M DuChanoisDepartment of Chemical and Biomolecular Engineering, Rice University, Houston, TX, USA.
Camille VioletDepartment of Chemical and Environmental Engineering, Yale University, New Haven, CT, USA.
John CumingsDepartment of Materials Science and Engineering, University of Maryland, College Park, MD, USA.ORCID http://orcid.org/0000-0002-5476-452X
Mingjiang ZhongDepartment of Chemical and Environmental Engineering, Yale University, New Haven, CT, USA.ORCID http://orcid.org/0000-0001-7533-4708
Menachem ElimelechDepartment of Chemical and Biomolecular Engineering, Rice University, Houston, TX, USA.ORCID http://orcid.org/0000-0003-4186-1563

Funding

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation) P400P2_199330U.S. Department of Energy (DOE) DE-SC0019112
6 · The paper itself

Abstract

Membrane-based liquid separations that selectively extract valuable ionic species from water can enhance resource circularity across industries. However, commercial membranes lack the selectivity required to target specific ions. Here we design crown-ether-based polymeric membranes for ion-ion separations using principles inspired by biological ion channels. Ultrathin membranes (~6 nm) are fabricated via interfacial polymerization of crosslinked 18-crown-6 units. The membranes preferentially sorb and transport potassium, which forms the most stable complexes with the crown ether motifs. Sorption experiments show strong potassium preference in mixed-salt environments, where competitive interactions increase selectivity. Transport measurements demonstrate selective permeation of potassium over competing monovalent and divalent cations, with selectivities of ~4 over cesium and lithium. The combination of ultrathin architecture, high crosslinking degree, and high binding-site density enables this behavior. This work establishes interfacial polymerization as a strategy to incorporate macrocycles into membranes for precise ion separation.

Identifiers

PMID41862472
PMCPMC13168650

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.