ArticleChemical science2026
Two-dimensional Pd-C bonded organometallic framework with dynamic packing transformations.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Traditional metal-organic frameworks (MOFs) are predominantly constructed through metal-oxygen (M-O) or metal-nitrogen (M-N) coordination bonds. However, the limited softness of M-O and M-N bonds restricts the incorporation of softer linkages involving low-valent or noble metals, as described by the hard-soft acid-base (HSAB) principle. Although metal-carbon (M-C) linkages have been proposed as a potential alternative, their limited reversibility and the scarcity of suitable multidentate ligands have hindered their broader implementation in MOF synthesis. In this study, we report the synthesis of a two-dimensional organometallic framework, PdOF-1, which bears direct palladium-carbon (Pd-C) bonds. PdOF-1 was synthesized
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