ArticleGreen chemistry : an international journal and green chemistry resource : GC2026
A one-pot organocatalytic process for the synthesis of cyclic carbonates from CO
Article in Green chemistry : an international journal and green chemistry resource : GC, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
Cyclic carbonates are usually obtained from coupling of carbon dioxide and epoxides. The latter are generally prepared through the selective oxidation of alkenes or other compounds containing a double bond. However, a one-pot route in which an alkene is directly converted into a cyclic carbonate would be preferable as it would circumvent the handling of generally toxic epoxides and would increase process efficiency in terms of energy, solvent and reagents usage. Here, we present an attractive strategy combining a recyclable oxidant (cumene hydroperoxide, CHP) with an inexpensive, metal-free organic halide salt as catalyst. These components act cooperatively promoting the oxidation of the chosen model substrate (styrene) and the cycloaddition of CO
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