ArticleMacromolecules2026
Different Crystalline Populations for Biopolyesters within Graphene-Based Nanopapers.
Article in Macromolecules, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
0 citing papers in PubMed.
No citing paper in PubMed yet.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The control and design of the semicrystalline structure of polymer binders within nanopapers based on graphene-related materials (GRM) may have a significant impact on the nanopapers' physical properties, including thermomechanical resistance and thermal conductivity. In this article, biopolyesters differing in methylene chain length between ester groups were studied, specifically using poly-(ε-caprolactone) (PCL) and poly-4-hydroxybutyrate (P4HB), with additional comparisons to polyglycolide (PGA). The crystallization behavior and crystalline structure of the polymers embedded in GRM nanopapers were studied by differential scanning calorimetry (DSC) and wide-angle X-ray scattering (WAXS). In particular, high melting point crystals originating from strong nucleation and strong molecular interactions with the GRM were observed with thermal stability dependent on the chemical structure of the polymer. The crystals having the highest melting temperatures, well above the equilibrium melting points of PCL and P4HB, are of particular interest. Besides their high thermal stability, these crystals cannot be fractionated through successive self-nucleation and annealing. At the same time, WAXS revealed distinct crystal diffraction reflections and relatively broad rings, suggesting the formation of crystals stabilized up to high temperatures by their interfacial adsorption onto GRM. These findings offer new insights into the mechanism of polymer crystallization at the interface with nanoparticles and may have implications for the development and application of hybrid organic/inorganic flexible nanopapers in electronic devices.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.