Development and Validation of a Digitizer-Based TCSPC System for Scintillation Decay Time Analysis via an Extended Convolution Model.

The development of high-fidelity digital twins for scintillation spectrometer detectors demands precise experimental characterization of timing parameters. This work presents a comprehensive solution comprising a digitizer-based time-correlated single-photon counting (TCSPC) system and an extended convolution model for decay time analysis. We introduce a physics-driven calibration principle, validating the system response against an independent physical benchmark to ensure fidelity. The proposed convolution model advances beyond the conventional model by incorporating additional parameters to account for scintillator-induced timing broadening and delay, thereby decoupling this effect from instrumental response. The model's descriptive power was statistically validated through its application to fast scintillators, while its physical accuracy was robustly confirmed through the precise extraction of typical decay times from slow scintillators. This methodology establishes a reliable workflow from measurement to parameterization, directly supplying the decoupled inputs required for the digital twins of scintillation detectors.