ArticleNanomaterials (Basel, Switzerland)2026
Iodine-Doped Carbon Nitride with Enhanced Electron Delocalization as Metal-Free Sulfur Hosts for Stable Lithium-Sulfur Batteries.
Article in Nanomaterials (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Suppressing the polysulfide shuttle effect and accelerating the sulfur redox kinetics remain pivotal challenges for advancing the practical viability of lithium-sulfur batteries (LSBs). In this study, an iodine-doped carbon nitride (I-CN) material was synthesized via a one-step annealing strategy and employed as a metal-free sulfur cathode host. Compared to its pristine counterpart, I-CN exhibits a substantially increased specific surface area, which facilitates the homogeneous dispersion of sulfur species. More importantly, the incorporation of iodine atoms disrupts the equilibrium of the electron cloud distribution within the CN framework, leading to enhanced electron delocalization. This electronic modulation not only significantly improves the charge transport properties of carbon nitride but also strengthens the adsorption of lithium polysulfides (LiPS) and promotes Li
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