ArticleOrganic letters2026
Copper-Catalyzed Amino-alkoxycarbonylation of Unactivated Alkenes: Synthesis of β-Amino Esters via Primary Tosyl Amidyl Radical.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 authors.
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Abstract
β-Amino acids serve as essential motifs in a wide array of bioactive compounds, pharmaceuticals, and natural products, playing a crucial role in the development of peptides and peptidomimetics. Transition-metal-catalyzed carbonylative functionalization represents an ideal strategy for synthesizing carbonyl-containing compounds. In this context, we disclose a primary tosyl amidyl radical initiated 1,2-amino-alkoxycarbonylation of unactivated alkenes, which offers a straightforward and efficient approach to synthesize β-amino acid derivatives.
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