ArticleChemical science2026
Red-light photoredox catalysis with bridged fluorescein derivatives: mechanistic insights and application to fluoride-responsive photopolymerization.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
6 authors.
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Abstract
We demonstrated bridged fluoresceins (BFLs) as a class of metal-free red-light photocatalysts that feature structurally tunable and switchable activity in aqueous solutions. Mechanistic studies using photoinitiated radical polymerizations under controlled atmospheres revealed that BFLs engage in efficient oxidative and reductive quenching cycles with co-initiators proceeding through excitation, intersystem crossing, single-electron transfer, and regeneration processes. Notably, molecular oxygen plays dual roles: (i) serving as a co-initiator through O
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Registered trials
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