ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Modular Generation of Alkyl Selenyl Radicals for the Synthesis of Alkyl Selenides via a Mechanochemical Approach.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Selenium-centered radicals: generation, detection and their relevance in chemistry and biology.RSC advances · 2026Review
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Authors and funding
9 authors.
Funding
Abstract
Radical-mediated selenylation has emerged as a powerful strategy for constructing carbon-selenium bonds. While effective for generating aryl selenyl radicals, current approaches for producing alkyl selenyl radicals remain underdeveloped. In this study, we present a mechanochemical approach that enables the modular generation of alkyl selenyl radicals from elemental selenium and alkyl halides, thereby advancing the hydroselenation of alkenes. The modular generation of alkyl selenyl radicals utilizes abundant and commercially available alkyl (pseudo)halides as radical precursors, activated through mechanical force to overcome selenium's inherent inertness. The reaction proceeds under ambient conditions with minimal solvent usage, achieving a broad substrate scope encompassing alkyl iodides, bromides, chlorides, and sulfonates. Notably, mechanistic experiments and density functional theory (DFT) calculations indicate that both PhSiH
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