ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Regulating Solvent-Separated Ion Pairs to Control Polysulfide Redox for Fast and Stable Room-Temperature Na-S Batteries.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The solvent-separated ion pairs in local high-concentration electrolytes (LHCE) have a profound influence on rechargeable sulfur-based batteries yet are always ignored. Herein, tailored solvent-separated ion pairs are engineered by tuning the diluent ratio in LHCE to boost sulfur redox kinetics in room-temperature sodium-sulfur (Na-S) batteries. The tailored solvent-separated ion pairs allow the sparingly dissolved polysulfides to enhance localized solid-liquid-solid transformation on reactive interfaces, so the LHCE decorated with the solvent-separated ion pairs preserves the global quasi-solid-state mechanism of sulfur while modulating its intrinsic sulfur redox kinetics. Consequently, Na-S batteries achieve excellent cyclability (fading rate of 0.017% per cycle over 2400 cycles at 1.0C) and outstanding rate performance (564 mA h g
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