ArticleJournal of the American Chemical Society2026
A Catalyst-Controlled Divergent Rearomatization of BN-Benzvalene.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
1 citing paper in PubMed.
- Modular and Stereoselective Synthesis of Cyclobutane β-Amino Alcohols.Angewandte Chemie (International ed. in English) · 2026Article
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Authors and funding
5 authors.
Funding
Abstract
Carbon-based benzvalene undergoes diverse rearrangements upon exposure to external stimuli. In this report, we investigate the thermal and metal-catalyzed rearomatization pathways of BN-benzvalene, a boron-nitrogen-containing valence isomer of benzene. Depending on the choice of metal catalyst, these transformations selectively yield either C5- or C3-functionalized 1,2-azaborines. The C5-isomer formation serves as a proof of concept for a new molecular photoswitch system, while the C3-isomer formation represents the functional group transposition on the 1,2-azaborine scaffold. Mechanistic investigations, such as deuterium labeling studies and DFT calculations, suggest distinct operative pathways for the generation of each isomer.
Identifiers
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Registered trials
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