ArticleJournal of the American Chemical Society2026
From Boron to Bismuth: The Pre-transmetalation Complex in the Aryl Transfer.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
4 authors.
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Abstract
B-to-Bi transmetalation is increasingly encountered as a key organometallic step in Bi-based protocols. Yet, akin to transition metal complexes, obtaining structural evidence of pre-transmetalation intermediates that lead to the aryl transfer from B to a metal is challenging and rare. Herein, we provide structural characterization of two unprecedented pre-transmetalation complexes linking B and Bi through a F- or an OH- bridge. Inspired by earlier studies on d-block elements, we establish two general pathways by which transmetalation can occur: the
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