Dynamic Covalent Networks of Molecular Clusters for Hard and Impact-Resistant Glass with Feasible Processability.

Haiyan Xiao, Jia-Fu Yin, Linjie Lan, Wei Liu-Fu, Panchao Yin

Abstract read

In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Haiyan XiaoState Key Laboratory of Luminescent Materials and Devices & South China Advanced Institute for Soft Matter Science and Technology, Guangdong Basic Research Center of Excellence for Energy & Information Polymer Materials, South China University of Technology, Guangzhou, P. R. China.

Jia-Fu YinSchool of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, P. R. China.

Linjie LanState Key Laboratory of Luminescent Materials and Devices & South China Advanced Institute for Soft Matter Science and Technology, Guangdong Basic Research Center of Excellence for Energy & Information Polymer Materials, South China University of Technology, Guangzhou, P. R. China.

Wei Liu-FuState Key Laboratory of Luminescent Materials and Devices & South China Advanced Institute for Soft Matter Science and Technology, Guangdong Basic Research Center of Excellence for Energy & Information Polymer Materials, South China University of Technology, Guangzhou, P. R. China.

Panchao YinState Key Laboratory of Luminescent Materials and Devices & South China Advanced Institute for Soft Matter Science and Technology, Guangdong Basic Research Center of Excellence for Energy & Information Polymer Materials, South China University of Technology, Guangzhou, P. R. China.ORCID https://orcid.org/0000-0003-2902-8376

Funding

Guangzhou Science, Technology and Innovation Commission 2023A04J1571Guangzhou Science, Technology and Innovation Commission 2024A04J6250National Natural Science Foundation of China 22241501National Natural Science Foundation of China 52203087National Natural Science Foundation of China 92261117Open Fund of the China Spallation Neutron Source Songshan Lake Science City DG24313519Postdoctoral Innovation Talent Support Program BX20220114

6 · The paper itself

Abstract

The polymeric organic glass suffers from the intrinsic tradeoffs among mechanical strengths, hardness, and impact resistance from their chain topologies, limiting their extensive applications. Herein, a polymer-free approach is developed for the fabrication of glass by crosslinking sub-nm particle using dynamic covalent bonds. The sub-nm polysilsesquioxane (POSS) particle is crosslinked by the dynamic boronic ester bonds when 1,4-phenylenediboronic acid is doped. The high crosslink density with homogeneous distribution of POSS endows the fabricated films with high elastic modulus (1.79 ± 0.43 GPa), hardness (0.36 ± 0.03 GPa), and transparency (>89.5% transmittance). The dynamic feature of the network enables excellent impact resistance beyond typical polymers by showing highenergy dissipation capacity (258.14 J cm

Indexed as

dynamic covalent bondimpact resistancemolecular clustermolecular granular materialsorganic glassrelaxation dynamics

Identifiers

PMID41769868

DOI10.1002/advs.202524238

PMCPMC13170207

What OpenQuestion holds

Textmetadata

LicenceCC BY

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.