Evidence map›Paper›PMID 41769144›Full record

ArticleMacromolecules2026

Healable and Reprocessable PETG-Based Dynamic Vinylogous Urethane Networks.

Chaninya Mak-Iad, José Augusto Berrocal, Georges J M Formon, Christoph Weder

Abstract read
In one paragraph

Article in Macromolecules, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Chaninya Mak-IadAdolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, Fribourg 1700, Switzerland.ORCID https://orcid.org/0009-0004-2969-7603
José Augusto BerrocalAdolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, Fribourg 1700, Switzerland.ORCID https://orcid.org/0000-0003-3435-8310
Georges J M FormonAdolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, Fribourg 1700, Switzerland.ORCID https://orcid.org/0000-0003-0900-9514
Christoph WederAdolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, Fribourg 1700, Switzerland.ORCID https://orcid.org/0000-0001-7183-1790

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The growing demand for sustainable materials calls for innovative strategies to extend the lifetime of polymers. In response to this challenge, we explored healable and reprocessable vinylogous urethane (VU) networks derived from commercially available glycol-modified polyethylene terephthalate (PETG). These materials were synthesized via Zn-catalyzed transesterification of PETG with ethylene glycol, end-functionalization of the resulting telechelics with bis-acetoacetate, and subsequent VU network formation using tris-(2-aminoethyl)-amine (TREN). The resulting networks combine high tensile strength (up to 48 MPa), high stiffness (0.9 GPa), and appreciable ductility (elongation at break up to 7%). An optimized network composition was reprocessed multiple times with minimal loss in performance and exhibits highly efficient healing behavior, recovering 95% of its original strength after 15 min at 180 °C. Overall, this work presents a simple and scalable route to transform a commercial high-performance polyester into a reprocessable and healable material that offers extended lifetime and improved sustainability.

Identifiers

PMID41769144
PMCPMC12947682

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.