ArticleMacromolecules2026
Charge Storage Mechanisms in Redox-Active Polymer Brushes.
Article in Macromolecules, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
3 authors.
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Abstract
Electroconductive polymer brushes grafted to conductive electrodes are investigated as model electrodes for aqueous supercapacitors using the Scheutjens-Fleer self-consistent field (SF-SCF) framework. The model self-consistently resolves polymer conformations, ion partitioning, and redox-mediated electron hopping under applied potentials (0-0.7 V). We show that solvent quality and grafting density govern brush swelling and counterion uptake, thus shaping the charge-potential response. In a good solvent, brushes provide volumetric charge storage throughout a swollen layer, while in a poor solvent, charging drives a collapsed-to-swollen transition that produces sharp capacitance peaks. During this transition, the differential capacitance reaches 15-30 F/m
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Registered trials
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