Evidence map›Paper›PMID 41768846›Full record

ArticleMacromolecules2025

Vitrimeric Behavior Revealed by Fast Scanning Calorimetry in Branched Polyglycerol Networks Cross-Linked by Reversible Enamine Bonds.

Vasiliki Maria Stavropoulou, Marta Aldecoa-Ortueta, Ester Verde-Sesto, Valerio Di Lisio, Anabel Lam, José A Pomposo, Angel Alegría, Daniele Cangialosi, Fabienne Barroso-Bujans

Abstract read
In one paragraph

Article in Macromolecules, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Vasiliki Maria StavropoulouMaterials Physics Center (CFM-MPC), CSIC-UPV/EHU, Paseo Manuel Lardizábal 5, 20018 Donostia-San Sebastián, Spain.ORCID https://orcid.org/0009-0009-8223-1438
Marta Aldecoa-OrtuetaMaterials Physics Center (CFM-MPC), CSIC-UPV/EHU, Paseo Manuel Lardizábal 5, 20018 Donostia-San Sebastián, Spain.ORCID https://orcid.org/0009-0001-3544-3501
Ester Verde-SestoMaterials Physics Center (CFM-MPC), CSIC-UPV/EHU, Paseo Manuel Lardizábal 5, 20018 Donostia-San Sebastián, Spain.ORCID https://orcid.org/0000-0001-8748-5140
Valerio Di LisioMaterials Physics Center (CFM-MPC), CSIC-UPV/EHU, Paseo Manuel Lardizábal 5, 20018 Donostia-San Sebastián, Spain.ORCID https://orcid.org/0000-0001-7729-8069
Anabel LamDonostia International Physics Center (DIPC), Paseo Manuel Lardizábal 4, 20018 Donostia-San Sebastián, Spain.ORCID https://orcid.org/0000-0001-5171-5020
José A PomposoMaterials Physics Center (CFM-MPC), CSIC-UPV/EHU, Paseo Manuel Lardizábal 5, 20018 Donostia-San Sebastián, Spain.ORCID https://orcid.org/0000-0003-4620-807X
Angel AlegríaMaterials Physics Center (CFM-MPC), CSIC-UPV/EHU, Paseo Manuel Lardizábal 5, 20018 Donostia-San Sebastián, Spain.ORCID https://orcid.org/0000-0001-6125-8214
Daniele CangialosiMaterials Physics Center (CFM-MPC), CSIC-UPV/EHU, Paseo Manuel Lardizábal 5, 20018 Donostia-San Sebastián, Spain.ORCID https://orcid.org/0000-0002-5782-7725
Fabienne Barroso-BujansMaterials Physics Center (CFM-MPC), CSIC-UPV/EHU, Paseo Manuel Lardizábal 5, 20018 Donostia-San Sebastián, Spain.ORCID https://orcid.org/0000-0002-9591-5646

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Dynamic covalent bonds formed by enamine have played a crucial role in the development of vitrimers by enabling their rearrangement and reprocessability. In this study, polymer networks obtained by cross-linking a β-ketoester-functionalized branched polyglycerol (PG-βkest) with three different diamines, i.e. diaminopropane (DAP), 2,2'-(ethylenedioxy)-bis-(ethylamine) (EDO) and Jeffamine D230 (Jeff) were generated through enamine bond formation enabling the formation of materials with tunable glass transition temperatures (

Identifiers

PMID41768846
PMCPMC12461918

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.