Evidence map›Paper›PMID 41767804›Full record

ArticleChemical science2026

Ultrafast dynamics in core-excited states probed by resonant Auger spectroscopy: pyrrole.

D M P Holland, H G McGhee, M Lamanec, D Nachtigallová, A Milosavljević, J D Bozek, E Muchová, R A Ingle

Abstract read
In one paragraph

Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

D M P HollandSTFC, Daresbury Laboratory Daresbury Warrington Cheshire WA4 4AD UK.ORCID https://orcid.org/0000-0003-1351-605X
H G McGheeDepartment of Chemistry 20 Gordon Street London WC1H 0AJ UK.
M LamanecInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences Flemingovo Náměstí 542/2 16000 Prague Czech Republic.ORCID https://orcid.org/0000-0002-7304-2207
D NachtigallováInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences Flemingovo Náměstí 542/2 16000 Prague Czech Republic.
A MilosavljevićSynchrotron SOLEIL L'Orme des Merisiers Gif-sur-Yvette 91192 France.
J D BozekSynchrotron SOLEIL L'Orme des Merisiers Gif-sur-Yvette 91192 France.ORCID https://orcid.org/0000-0001-7486-7238
E MuchováDepartment of Physical Chemistry, University of Chemistry and Technology in Prague Technická 5 Prague 166 28 Czech Republic muchovae@vscht.cz.ORCID https://orcid.org/0000-0002-3768-6208
R A IngleDepartment of Chemistry 20 Gordon Street London WC1H 0AJ UK r.ingle@ucl.ac.uk.ORCID https://orcid.org/0000-0002-0566-3407

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We present high-resolution resonant Auger spectra of pyrrole at both the nitrogen and carbon edges. Through comparison to high-level quantum chemical calculations and a linear vibronic coupling model, we show how resonant Auger spectroscopy can capture the out-of-plane nuclear motions that occur during the few femtosecond core-hole relaxation processes. We also demonstrate how, in scenarios where there are near-degenerate electronic transitions in the X-ray absorption spectrum that cannot be resolved experimentally, resonant Auger can be used as a probe of the underlying electronic structure. Overall, resonant Auger is a technique capable of revealing detailed information about core-excited molecules that cannot be recovered through X-ray absorption or photoelectron spectroscopy alone.

Identifiers

PMID41767804
PMCPMC12946931

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.