High-Porosity Conjugated Polyelectrolytes Synthesized via Sonogashira-Hagihara Coupling in Concentrated Emulsions: Robust Adsorptive-Photocatalytic Hydrogels for Water Pollutant Removal.

Aleksander Saša Markovič, Siebe Lievens, Emeline Hanozin, Milica Velimirovic, Albin Pintar, Sebastijan Kovačič

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Article in Macromolecules, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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6 authors.

Aleksander Saša MarkovičCatalysis and Organic Synthesis research group, Laboratory for Organic and Polymer Chemistry, Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova 17, SI-2000 Maribor, Slovenia.

Siebe LievensFlemisch Institute for Technological Research (VITO), Boeretang 200, 2400 Mol, Belgium.

Emeline HanozinFlemisch Institute for Technological Research (VITO), Boeretang 200, 2400 Mol, Belgium.

Milica VelimirovicFlemisch Institute for Technological Research (VITO), Boeretang 200, 2400 Mol, Belgium.

Albin PintarDepartment of Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, SI-1001 Ljubljana, Slovenia.

Sebastijan KovačičCatalysis and Organic Synthesis research group, Laboratory for Organic and Polymer Chemistry, Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova 17, SI-2000 Maribor, Slovenia.ORCID https://orcid.org/0000-0003-2664-9791

Funding

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6 · The paper itself

Abstract

Conjugated polyelectrolyte (CPE) hydrogels uniquely combine π-conjugation, ionic functionality, and water compatibility in a single-polymer network. This work reports on the design, synthesis, and application of high-porosity CPE hydrogels obtained via the Sonogashira-Hagihara cross-coupling reaction as a polymerization chemistry in a high internal phase emulsion (HIPE) template. In this way, we combine the hydrophilic and π-conjugated electronic properties of CPEs with the high porosity of polymerized high internal phase emulsions (polyHIPEs or PHs), enabling the development of a multifunctional polymer platform. High-porosity CPE-PHs exhibit a surface area of up to 355 m

Identifiers

PMID41767482

DOI10.1021/acs.macromol.5c02304

PMCPMC12854763

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