ArticleMacromolecules2025
Unraveling the Temperature-Dependent Relaxation Dynamics of Ionic Liquid-Plasticized Compleximers.
Article in Macromolecules, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Stretchable Water-Free Liquid Crystalline Polyelectrolyte Complexes.ACS applied polymer materials · 2026Article
- A molecular dynamics study of the structure and dynamics of screened polyelectrolyte complex materials.Soft matter · 2026Article
- Ionic glass formers show an inverted relation between fragility and non-exponential alpha-relaxation.Nature communications · 2026Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Polyelectrolytes with ionic domains screened by bulky hydrophobic segments form processable, hydrophobic complexes called "compleximers". Ionic liquids, which are chemically similar, further plasticize compleximers, yet the mechanisms behind their plasticization effects and distribution within the complexes remain unclear. This study examines the relaxation dynamics of plasticized compleximers across multiple length scales using rheology, fluorescence recovery after photobleaching (FRAP), and broadband dielectric spectroscopy (BDS). The incorporation of ionic liquids into compleximers reduces their glass transition temperature (
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