Evidence map›Paper›PMID 41760948›Full record

ArticleNature materials2026

Molecular factors controlling charge pair generation in organic photovoltaic materials.

Lucy J F Hart, Daniel G Medranda, Shi Wei Yuan, Linnea Lindh, Jolanda S Müller, Hanbo Yang, Hugo Gerard, Tianyu Zhao, Arianna Quesada-Ramirez, Mariano Campoy-Quiles and 3 more

Abstract read
In one paragraph

Article in Nature materials, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Lucy J F Hart *Department of Physics, Imperial College London, London, UK.ORCID http://orcid.org/0000-0002-6269-4672
Daniel G Medranda *Department of Physics, Imperial College London, London, UK.ORCID http://orcid.org/0009-0004-0476-4195
Shi Wei Yuan *Department of Physics, Imperial College London, London, UK.ORCID http://orcid.org/0009-0001-1156-9118
Linnea Lindh *Department of Physics, Imperial College London, London, UK.ORCID http://orcid.org/0000-0002-1940-0376
Jolanda S MüllerDepartment of Physics, Imperial College London, London, UK.ORCID http://orcid.org/0009-0005-7297-7827
Hanbo YangDepartment of Physics, Imperial College London, London, UK.ORCID http://orcid.org/0000-0002-9437-1982
Hugo GerardDepartment of Physics, Imperial College London, London, UK.
Tianyu ZhaoDepartment of Physics, Imperial College London, London, UK.ORCID http://orcid.org/0009-0001-5063-8737
Arianna Quesada-RamirezDepartment of Nanostructured Materials, Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Bellaterra, Spain.ORCID http://orcid.org/0009-0006-3396-4481
Mariano Campoy-QuilesDepartment of Nanostructured Materials, Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Bellaterra, Spain.ORCID http://orcid.org/0000-0002-8911-640X
Mohammed AzzouziLaboratory for Computational Molecular Design (LCMD), Institute of Chemical Sciences and Engineering, Ecole Polytechnique Federal de Lausanne (EPFL), Lausanne, Switzerland. mohammed.azzouzi@epfl.ch.ORCID http://orcid.org/0000-0001-5190-9984
Flurin D EisnerDepartment of Physics, Imperial College London, London, UK. f.eisner@qmul.ac.uk.ORCID http://orcid.org/0000-0001-5507-4961
Jenny NelsonDepartment of Physics, Imperial College London, London, UK. jenny.nelson@imperial.ac.uk.ORCID http://orcid.org/0000-0003-1048-1330

Funding

EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council) 742708RCUK | Engineering and Physical Sciences Research Council (EPSRC) EP/TO28513/1Research Councils UK (RCUK) EP/Z533361/1
6 · The paper itself

Abstract

Through remarkable advances in materials design, the efficiency of photovoltaic energy conversion in molecular materials has risen from 1% to over 20% within 2 decades. Some recent reports argue that charge photogeneration can occur directly in neat films of the best-performing molecular materials, and that this process may assist current generation in heterojunction devices. Here we address this assertion by combining experimental measurements of charge generation in single-component and heterojunction devices with a computational model of the generation and evolution of delocalized excited states in such systems. We identify key molecular parameters that are likely to assist charge generation in high-performance materials, including the exciton binding energy, reorganization energy, energetic disorder, electronic coupling and the molecular packing motif. We show that including state delocalization is critical to the results. While we find that charge generation in single domains is unlikely to drive photocurrent generation in low-offset heterojunctions, the same molecular parameters favour charge generation in both device architectures.

Identifiers

PMID41760948
PMCPMC13323082

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.