ArticlePrecision chemistry2026
Precise Construction of Helical Unimolecular Micelles from Poly(phenylacetylene)s for Tunable Circularly Polarized Luminescence and Sensing.
Zhenqian Zhang, Yuhang Wei, Xiaoguang Qiao, Junle Zhang, Mengjie Zhou, Yanjie He, Wenjie Zhang, Zhe Cui, Ge Shi, Xinchang Pang
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In one paragraphArticle in Precision chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 · Who and what moneyAuthors and funding
10 authors.
Zhenqian ZhangHenan Joint International Research Laboratory of Living Polymerizations and Functional Nanomaterials, Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.
Yuhang WeiHenan Joint International Research Laboratory of Living Polymerizations and Functional Nanomaterials, Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.
Xiaoguang QiaoHenan Joint International Research Laboratory of Living Polymerizations and Functional Nanomaterials, Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.ORCID https://orcid.org/0000-0002-4379-5398 Junle ZhangFaculty of Engineering, Huanghe Science and Technology College, Zhengzhou 450063, China.
Mengjie ZhouHenan Joint International Research Laboratory of Living Polymerizations and Functional Nanomaterials, Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.
Yanjie HeHenan Joint International Research Laboratory of Living Polymerizations and Functional Nanomaterials, Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.ORCID https://orcid.org/0000-0002-7954-5817 Wenjie ZhangHenan Joint International Research Laboratory of Living Polymerizations and Functional Nanomaterials, Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.ORCID https://orcid.org/0000-0003-3254-4988 Zhe CuiHenan Joint International Research Laboratory of Living Polymerizations and Functional Nanomaterials, Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.ORCID https://orcid.org/0000-0001-7557-0129 Ge ShiHenan Joint International Research Laboratory of Living Polymerizations and Functional Nanomaterials, Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.ORCID https://orcid.org/0000-0001-8493-2777 Xinchang PangHenan Joint International Research Laboratory of Living Polymerizations and Functional Nanomaterials, Henan Key Laboratory of Advanced Nylon Materials and Application, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.
Funding
No grant is acknowledged in the PubMed record.
6 · The paper itselfAbstract
Chiral nanocomposites have attracted much attention due to their fascinating size-dependent characteristics. Such nanomaterials could be precisely synthesized by templates from randomly coiled unimolecular micelles with poor chiroptical activities. Helical polymers possessing secondary chirality usually display stronger chiral induction than random-coiled polymers do. However, the controllable preparation of helical unimolecular micelles still remains challenging, which hinders the investigation into the effect of morphology and size on chiroptical properties. In this study, multiarmed star-shaped poly-(phenylacetylene)-s (PPAs) with target composition, molecular weight, and size were precisely prepared from the multisited initiator via living polymerization. Based on acid-base interactions, chiral transfer from PPAs to various dyes was accomplished in composite membranes and suspension. Notably, the chiral nanocomposites consisting of star-shaped PPAs displayed enhanced helical stability, Cotton effect, and circularly polarized luminescence (CPL) compared with linear analogues. Furthermore, this system displayed the triple-mode (photoluminescence, circular dichroism, and CPL) detection toward the volatile organic compound for environmental monitoring.
Indexed as
Chiral inductionCircularly polarized luminescencePoly(phenylacetylene)sPrecise synthesisUnimolecular micelles
Identifiers
PMID41756617
PMCPMC12933480
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