ArticleJACS Au2026
Merging Double Hydrogen Atom Transfer and Stepwise Proton-Coupled Electron Transfer for γ‑C-H Hydrazination of Alcohols.
Article in JACS Au, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A cobalt-(salen)-catalyzed γ-C-H hydrazination of alcohols is unveiled, merging a double hydrogen atom transfer (HAT) and a proton-coupled electron transfer (PCET) within a single catalytic cycle. The transformation harnesses metal-hydrogen atom transfer-induced radical translocation and electrophilic azodicarboxylate coupling to achieve remote C-H functionalization under mild and sustainable conditions. Mechanistic investigations (EPR, UV-vis, and spin-trapping) reveal cobalt oxidation state modulation and transient radical intermediates, while DFT analysis elucidates the double HAT/PCET pathway and site selectivity. This strategy offers an efficient and sustainable route from simple alcohols to γ-hydrazino and γ-amino alcohols.
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