Photocatalytic C-C Coupling by a Au(I) Complex: Mechanistic Elucidation and SET Modulation.

Yan Jiang, Le-Jie Liu, Jia-Jia Ma, Xiao-Ya Dou, Ling-Ya Peng, Ganglong Cui, Yu Fang

Abstract read

In one paragraph

Article in JACS Au, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

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2 · The registry

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4 · The record

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PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Yan JiangShaanxi Provincial Key Laboratory of New Concept Sensors and Molecular Materials, Key Laboratory of Applied Surface and Colloids Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China.

Le-Jie LiuShaanxi Provincial Key Laboratory of New Concept Sensors and Molecular Materials, Key Laboratory of Applied Surface and Colloids Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China.

Jia-Jia MaKey Laboratory of Theoretical and Computational Photochemistry, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China.

Xiao-Ya DouShaanxi Provincial Key Laboratory of New Concept Sensors and Molecular Materials, Key Laboratory of Applied Surface and Colloids Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China.

Ling-Ya PengShaanxi Provincial Key Laboratory of New Concept Sensors and Molecular Materials, Key Laboratory of Applied Surface and Colloids Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China.

Ganglong CuiKey Laboratory of Theoretical and Computational Photochemistry, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China.ORCID https://orcid.org/0000-0002-9752-1659

Yu FangShaanxi Provincial Key Laboratory of New Concept Sensors and Molecular Materials, Key Laboratory of Applied Surface and Colloids Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China.ORCID https://orcid.org/0000-0001-8490-8080

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Photocatalytic C-C coupling reactions mediated by molecular complexes represent an advancing field of research, in which Au-based catalysts have demonstrated significant potential. Herein, we employ an integrated computational strategy: incorporating MS-CASPT2, DFT, and kinetic analyses of fluorescence, phosphorescence, intersystem crossing, internal conversion, and electron transfer processes to unravel the mechanistic intricacies between aryldiazonium salts and alkynyl-silanes catalyzed by a naphthalene-di-imide-functionalized N-heterocyclic carbene Au-(I) complex, [(NDI-NHC)-Au-Cl]. Upon photoexcitation, a four-state model (S

Indexed as

C−C CouplingMarcus TheoryMS-CASPT2Nonradiative ProcessSingle Electron Transfer

Identifiers

PMID41755828

DOI10.1021/jacsau.5c01536

PMCPMC12933309

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LicenceCC BY-NC-ND

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.